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Hydrogen Generator Gas For
Vehicles And Engines Vol. 3&4
These Volumes present an explanation of how biomass can be converted to a gas in a Downdraft Gasifier and details for designing, testing, operating, and manufacturing Gasifiers and Gasifier Systems, as well as knowledge that was put into practical use during World War II including detailed step-by-step procedures for constructing a Producer Gas Generator for fueling internal combustion engines. HYDROGEN GENERATOR GAS FOR VEHICLES AND ENGINES: Volumes 3 & 4 also gives extensive detail on biomass fuels, gas testing and cleanup instrumentation, and safety considerations that will be extremely valuable to all those who work with Gasifiers at any scale.
The combustion of biomass in wood stoves and industrial boilers has increased dramatically in some areas, and forest, agricultural, and paper wastes are being used extensively for fuels by some industries. However, more extensive biomass use still waits for the application of improved conversion methods, such as gasification, that match biomass energy to processes currently requiring liquid and gaseous fuels. Examples of such processes include glass, lime, and brick manufacture; power generation; and transportation.
Biomass, like coal, is a solid fuel and thus is inherently less convenient to use than the gaseous or liquid fuels to which we have become accustomed. An overview of various processes now in use or under evaluation for converting biomass to more conventional energy forms such as gas or liquid fuels is provided in this book. It shows how sunlight is converted to biomass through either traditional, activities (e.g., agriculture and silviculture) or via new innovative techniques that have been developed such as energy plantations, coppicing, and algaeculture.
In one sense, biomass gasification is already a well proven technology. Approximately one million downdraft Gasifiers were used to operate cars, trucks, boats, trains, and electric generators in Europe during World War II, and the history of this experience is outlined in this book. However, the war's end saw this emergency measure abandoned. Development of biomass gasification was disrupted in 1946 as the war ended. and inexpensive (150/gal) gasoline became readily available. The magnitude of damage inflicted on Gasifier technology by this disruption can be seen by the fact that it was difficult for even the "advanced" technology of the 1980s to achieve .on tests what was routine operation in the 1940s. The design, research, and manufacturing teams of that decade have all disbanded. We have from the past only that small fraction of knowledge that has been published, whereas the large bulk of firsthand experience in operation design has been lost and forgotten.
Gasification was rediscovered in an era of fuel shortages and higher oil prices, in its rebirth, however, the existing technology uncovered major problems in connection with effluent and gas cleanup and the fuel supply, which were less important during the emergency of World War II. Today, these problems must be solved if biomass gasification is to reemerge as a fuel source but with space-age advances in materials and control systems available for use in today's process designs, a continuous development effort and lively open exchange should enable us to incorporate latter-day chemical and chemical engineering techniques to build clean, convenient, and reliable systems.
Biomass is a renewable fuel, provided that consumption does not exceed annual production. The biomass feedstock is often a low-cost byproduct of agriculture or silviculture. As such, Biomass could easily supply at least 20% of U.S. energy needs on a renewable basis.
Ultimately though, the accelerated use of gasification technologies depends upon their ability to compete with fossil fuels, which in turn depends on unpredictable factors about resources, economics, and political conditions. At present, gasification and other energy processes are being developed slowly in the United States because of relatively plentiful supplies of low-cost gaseous and liquid fossil fuels. However, political changes and volatile conflicts in key oil production regions could rapidly and dramatically alter this situation, as witnessed during WWII, the OPEC oil crises of the seventies and in the aftermath of Hurricane Katrina eternally cheap oil cannot just be taken for granted.
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| The stratified, downdraft design has a number of advantages over the WWII Imbert gasifier. The open top permits fuel to be fed more easily and allows easy access. The cylindrical shape is easy to fabricate and permits continuous flow of fuel. No special fuel shape or pretreatment is necessary; any blocky fuel can be used. |
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Biomass can contain more than 50% moisture (wet basis) when it is cut; it is generally desirable to dry biomass containing more than 25% moisture (wet basis) before gasification. Drying often can be accomplished using waste heat or solar energy. If the temperature of the drying air is too high, the outer surfaces of the chunk will become dry and begin to pyrolyze before the heat can reach the center. For efficient drying, hot air, which if cooled to 60°-80°C would be moisture saturated, is preferred. The moisture slows feedstock drying (as well as slowing surface pyrolysis). Thus more air is required, improving the drying process (Thompson 1981). During operation of a gasifier and engine combination, 1-in. wood chips can be dried from 50% to 5% moisture content, with drying capacity to spare, using a 20-minute residence time with the hot engine exhaust, tempered with 90% recycle of dryer gases.
Commercial dryers are available in many forms and sizes, and it is beyond the scope of this handbook to recommend such equipment for commercial-scale operations. A simple batch dryer for drying small quantities in shown in Fig. 3-6 and a commercial dryer is shown in Fig. 3-7.
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Cellulose is a linear polymer of anhydroglucose units; hemicellulose is a mixture of polymers of 5- and 6-carbon anhydrosugars, and lignin is an irregular polymer of phenyl propane units. In biomass, these three polymers form an interpenetrating system, or block copolymer, that varies in composition across the cell wall. Nevertheless, in large samples, there is a relatively *constant atomic ratio of CH1.400.6. (The ratios will vary slightly with species. Coal is typically about CH0.900.1 but varies more widely in composition.) The relationship between solid, liquid, and gaseous fuels is easily seen in Fig. 4-1(a) where the relative atomic concentrations of carbon, hydrogen, and oxygen are plotted for a variety of fuels. Here it is seen that the solid fuels, biomass, coal and charcoal, lie in the lower left segment of the diagram; liquid and gaseous hydrocarbon fuels lie in the upper left section; CO and. H2 are joined by the bisector of the triangle; and the combustion products of fuels, CO2 and H20, lie on a vertical line on the right.
Thermal conversion processes for biomass are indicated by the arrows of Fig. 4-1(b). Here it is seen that the conversion processes move the chemical composition of biomass to liquid or solid fuel regions, either by biological or thermal means. In some cases (such as oxygen/air gasification), the processes are spontaneous; in other cases (such as steam gasification) considerable energy must be expended to cause the change.
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Biomass Pyrolysis
Pyrolysis is the breaking down (lysis) of a material by heat (pyro). It is the first step in the combustion or gasification of biomass. When biomass is heated in the absence of air to about 350°C (pyrolysis), it forms charcoal (chemical symbol: C), gases (CO, CO2, H2, H20, CH4), and tar vapors (with an approximate atomic makeup of CH1200.5). The tar vapors are gases at the temperature of pyrolysis but condense to form a smoke composed of fine tar droplets as they cool.
All the processes involved in pyrolysis, gasification, and combustion can be seen in the flaming match of Fig. 4-2. The flame provides heat for pyrolysis, and the resulting gases and vapors burn in the luminous flame in a process called flaming combustion. After the flame passes a given point, the char may or may not continue to burn (some matches are chemically treated to prevent the charcoal from smouldering). When the match is extinguished, the remaining wood continues to undergo residual pyrolysis, generating a visible smoke composed of the condensed tar droplets.
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Cyclone Separators
Cyclones are simple and inexpensive dust and droplet separators; they are widely used on gasifiers and will be discussed in extra detail in this section.
Hot gas cyclone separators are well suited to remove solid particles larger than 10 Jim as a prefilter for the gas cooler and fine particle removal, as shown in Fig. 8-3, for a vehicle gasifier of the 1939-1945 era.
Cyclone separators are also used widely in industrial processes. The principles are well-developed, and designs are easily scaled to the necessary size. High-efficiency cyclone separators can be fabricated readily by a sheet-metal or welding shop. Cyclone design parameters are presented in this section and at greater length in Perry (1973), • Calvert (1972), and Strauss (1975). Unfortunately, the small cyclones required for small gasifiers are not available commercially, so they must be custom designed and fabricated.
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